کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7825506 1502925 2018 28 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Kraft lignin ameliorates degradation resistance of starch in urea delivery biocomposites
ترجمه فارسی عنوان
لیگنین کرافت باعث کاهش مقاومت تخریب نشاسته در زیست کامپوزیت های تحویل اوره می شود
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی
Starch high biodegradation is a limitation for commercialization of starch derived slow release fertilizers (SRFs). To reduce starch biodegradation, kraft lignin (5%-20%) was tested for reducing the starch biodegradability in urea crosslinked starch (UcS) films, reported as here as a SRF. Biodegradability tests were conducted under anaerobic soil microcosm for period of 60 days. Fourier transformed infrared spectroscopy results showed an absence of peak at 1776 cm−1 (pertained to oxidation of starch) in biodegraded lignin reinforced films. Thermogravimetric analysis of lignin reinforced films showed deceleration in the biodegradability rates, which were clearly evident from increase in the decomposition temperature at 5% weight loss, ∼67.0 °C and at maximum weight loss, ∼13.6 °C. Besides, char contents were increased, ∼11.3%. Molecular weight distribution indicated the lignin's effect on conservation the molecular weight and polydispersity of starch in films. Lignin role in protecting the starch morphology was confirmed through optical microscopy results, which showed a less change for feret mean and particle area of starch particles. Further, lignin increased average roughness, ∼1.04 to 4.76 times for biodegraded films, possibly due to accumulation of lignin after loss of starch in films. Further, this study concluded that lignin influenced effectively the reduction in starch biodegradability under anaerobic soil microcosm. Thus, lignin could be used in urea crosslinked starch and other similar films, for controlling the starch biodegradability and improving the SRF formulations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 65, February 2018, Pages 398-406
نویسندگان
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