کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7826468 | 1503039 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Biodegradable photocross-linked polymers of glycerol diglycidyl ether and structurally different alcohols
ترجمه فارسی عنوان
پلیمرهای مرتبط با فوتوکراس زیستی تجزیه شده از گلیسرول دی گلیکیدیل اتر و الکل های ساختاری متفاوت
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
Structurally different alcohols, e.g. 1,4-cyclohexanedimethanol, 1,1,1-tris(hydroxymethyl)propane, hydroquinone, and bisphenol A, were used for photocross-linking of glycerol diglycidyl ether on purpose to study structure-properties relationship of the resulting polymer films. Kinetics of photocross-linking was investigated by photorheometry. Dependencies of chemical structure and amount of alcohol used on mechanical, thermal, rheological properties, and biodegradability of the synthesized polymers were studied. The addition of alcohol resulted in an increase of the rate of photocross-linking of glycerol diglycidyl ether. The amount of alcohol used had more considerable effect on properties of polymers than chemical structure of alcohol. The higher amount (>Â 20Â mol%) of alcohol led to the easier association of alcohol molecules with released protons and thus deteriorated the properties of the cross-linked polymers. However, the addition of alcohols increased the biodegradability of resulted polymers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 122, January 2018, Pages 42-50
Journal: Reactive and Functional Polymers - Volume 122, January 2018, Pages 42-50
نویسندگان
Sigita Kasetaite, Jolita Ostrauskaite, Violeta Grazuleviciene, Danguole Bridziuviene, Ruta Budreckiene, Egidija Rainosalo,