Sol–gel derived hydrogen annealed ZnO:Al films for silicon solar cell application

A study of the effect of hydrogen annealing on antireflection and surface passivation properties of sol–gel derived aluminum rich zinc oxide (AZO) films coated on silicon wafers has been done in 300–600 °C temperature range. The minority carrier lifetime in silicon wafers coated with AZO films was measured using microwave photoconductive decay (μ-PCD) technique. After annealing of AZO coated silicon wafer in hydrogen ambient for 30 min between 400 and 600 °C the effective minority carrier lifetime τeff improved above the initial value of ∼16 μs and attained a maximal value of ∼71 μs for annealing at 500 °C. It may be that above 400 °C the molecular hydrogen gets dissociated into atomic hydrogen in presence of Al induced defects at the AZO coated silicon surface and passivates them by formation of Si–H–Al complex. The annealing in air in the same temperature range did not affect the lifetime. AZO films annealed at 500 °C in hydrogen or air show high transmittance in 400–1200 nm wavelength range and are suitable as AR coatings for silicon solar cells. We have applied a hydrogen annealed AZO antireflection coating on n+ front surface and an equally thick hydrogen annealed AZO coating on the p-back surface of an n+-p multi crystalline silicon solar cell. The observed improvement in Jsc, Voc values of the cell established that while AZO film on front acted as a good AR coating the AZO film on the back surface passivated the back surface effectively.

Variation of effective minority carrier lifetime of AZO coated silicon wafers sintered in (a) air (--
• --) and (b) hydrogen (__■__) ambient.Figure optionsDownload as PowerPoint slideHighlights
► Sol–gel derived aluminum rich zinc oxide (AZO) films on silicon wafers are studied from the view point of antireflection and surface passivation.
► Significant improvement in effective minority carrier lifetime is observed in the samples annealed in hydrogen between 400 and 600 °C.
► AZO films annealed in hydrogen ambient at 500 °C show high transmittance in 400–1200 nm wavelength range.
► Preliminary results of AZO film on silicon solar cell show improvement in cell performance parameters.