کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7839483 | 1505710 | 2017 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Using soft x-ray absorption spectroscopy to characterize electrode/electrolyte interfaces in-situ and operando
ترجمه فارسی عنوان
با استفاده از طیف سنجی جذب اشعه ایکس نرم برای تشخیص واسطهای الکترود / الکترولیت در محل و اپندود
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کلمات کلیدی
رابط مایع جامد / مایع دو لایه الکتروشیمیایی، طیف سنجی جذب اشعه ایکس، سلول مایع،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
The interfaces between electrode and electrolyte play a vital role in various electrochemical systems. However, the understanding of such embedded interfaces and interfacial processes is still limited partly because of the short of proper characterizations tools, especially in-situ/operando techniques. In the past decade, substantial effort has been devoted in the development of in-situ/operando techniques to investigate the solid/liquid interfaces. One successful approach is the combination of in-situ liquid cells and soft x-ray absorption spectroscopy (sXAS). In this review, we showcased several recent examples using such liquid-cell-based in-situ/operando sXAS method to study different aspects of the electrode/electrolyte interface under reaction conditions, including the adsorption and deposition of solute species on electrode surface, morphological and chemical changes of electrode surface, and potential-dependent orientations of interfacial solvent molecules. These examples demonstrated capability of such in-situ/operando sXAS techniques in providing element- and chemical-sensitive interfacial information. This in-situ/operando sXAS technique also opens the way to the investigation of various solid/liquid interfaces in other important heterogeneous reactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 221, November 2017, Pages 2-9
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 221, November 2017, Pages 2-9
نویسندگان
Yifan Ye, Cheng Hao Wu, Liang Zhang, Yi-Sheng Liu, Per-Anders Glans-Suzuki, Jinghua Guo,