کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7839642 | 1505859 | 2018 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
D-Ï-A type barbituric derivatives: Aggregation induced emission, mechanofluorochromic and solvatochromic properties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Four new barbituric derivatives that bears the furan and thiophene and the 1,3-dimethyl barbituric acid moiety, has been synthesized. These D-Ï-A type conjugated compounds showed obvious intramolecular charge transfer (ICT) properties, which were evidenced by theoretical calculations and spectral analysis. The compounds exhibited Aggregation induced emission (AIE) characteristic. TOB-1 and FTB-1 were quite weakly emission in pure THF, while a significant AIE effect was observed in water/THF (fw =â¯70% and 90%) mixtures with a large AIE factor of 40.5 and 46.8. Barbituric acid derivatives with thiophene electron donating group possess the distinct mechanofluorochromic (MFC) behavior. The original powder of FTB-1, BFTB-2 and TFTB-4 could emit strong orange-yellow (614â¯nm), orange-red (663â¯nm) and yellow (571â¯nm) light under UV irradiation, while the fluorescence color changed into orange (629â¯nm), red (691â¯nm) and orange yellow (583â¯nm) emission after grinding, respectively, a red shift of 15, 28 and 12â¯nm was observed, respectively. Among them, the emission color of compound BFTB-2 can be observed by naked eyes. Such mechanochromism was reversible upon the treatment of grinding and fuming with CH2Cl2. The XRD studies of the powders showed that the MFC behavior of FTB-1 and BFTB-2 might be switched reversibly under the stimulus of external force because of the decrease in crystallinity. The resultant red shift of TFTB-4 was attributed to the planarization induced by grinding.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 203, November 2018, Pages 50-58
Journal: Journal of Luminescence - Volume 203, November 2018, Pages 50-58
نویسندگان
Kai Li, Xi Su, Yixuan Wang, Furong Tao, Yuezhi Cui, Huayong Zhang, Tianduo Li,