کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7839753 | 1505859 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Near-infrared luminescent materials: From β-diketonate ytterbium complexes to β-diketonate-ytterbium-complex@PMMA thin film
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In view of the potential application of NIR luminescence in biology, a series of four new 3,5-Heptanedione (β-diketonate) ytterbium complexes, e.g. [Yb(L)3(H2O)2] (1), [Yb(L)3(2,2â²-bpy)] (2), [Yb(L)3(dpq)] (3) and [Yb(L)3(dppz)] (4) have been designed and isolated. Crystal structures analysis show that all complexes 1-4 exhibit the similar mononuclear structure, in which the central Yb3+ ion is eight-coordinated forming the square-anti-prismatic geometry. NIR luminescence of all complexes 1-4 shows strong characteristic emission of Yb3+ ions. To improve the mechanical and thermal stability, complex 1 was further doped into poly-(methyl methacrylate) (PMMA) for preparing a thin film (1@PMMA). Their thermal stability and NIR luminescence were essentially enhanced in contrast to that for complex 1. This NIR luminescent thin film may be of potential applications in biological dictation and luminescent probe.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 203, November 2018, Pages 473-480
Journal: Journal of Luminescence - Volume 203, November 2018, Pages 473-480
نویسندگان
Siqi Fan, Xu Yao, Jingfang Li, Weizuo Li, Guangming Li,