کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7840740 | 1505868 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Tailoring luminescent colour and life persistence of undoped CdSiO3
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
In this work, undoped CdSiO3 samples with different luminescence spectra and light persistence were obtained by controlling the parameters of sol-gel synthesis. The process of monoclinic phase formation was monitored through XRD and TG-DTA measurements, combined to microstructural characterization using FTIR and SEM. The optical energy bandgap (Eg) of CdSiO3 was estimated from Tauc equation and indicates the dependency of bandgap energy on the starting pH used for synthesis. Three main peaks could be identified from PL and XEOL spectra, at 590Â nm, 490Â nm and 406Â nm. Their relative intensities yielded overall distinct luminescence colours, such as indigo or red. The luminescent mechanisms of CdSiO3 related to an intrinsic defect (VCd) were further investigated to show its key role in the charge trapping that causes long lasting luminescence.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 194, February 2018, Pages 535-541
Journal: Journal of Luminescence - Volume 194, February 2018, Pages 535-541
نویسندگان
Damon F. Farias, Carolina M. de Abreu, Suellen Maria V. Novais, Zélia S. Macedo,