Solvent effect on the electrochemical oxidation of N,N,N′,N′-tetramethyl-1,4-phenylenediamine. New insights into the correlation of electron transfer kinetics with dynamic solvent effects

The effects of different solvents on the electrochemical oxidation of N,N,N′,N′-tetramethyl-1,4-phenylenediamine (TMPD) was studied experimentally using the cyclic voltammetry and theoretically according to the Marcus theory.354