کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7885762 | 1509784 | 2018 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Raman scattering and infrared reflectivity study of orthorhombic/monoclinic LaTiNbO6 microwave dielectric ceramics by A/B-site substitution
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The structure origin of microwave dielectric properties in A/B-site substituted LaTiNbO6 ceramics with different crystal structures was explored by means of Raman scattering and infrared reflection spectra. Compared with the monoclinic (M) phase, the broadening of the Raman modes associated with B-O stretching and bending vibrations in the orthorhombic (O) phase was believed to be a result of the increased octahedral distortion. The Raman mode at 659â¯cmâ1 was assigned to the stretching vibration of B-O-B and O-B-O bonds in the unique interlayer chain structure of O phase. The Raman modes of the BO6 tilting within 340-520â¯cmâ1 suggest that different octahedral connection ways should be one of the vital reasons why M and O phases own opposite-sign temperature coefficient of resonance frequency Ïf. Moreover, the result of infrared reflection spectrum fitted with a four-parameter semiquantum model indicates that the dielectric response of both M and O phases would mainly originate from the A-BO6 external vibrations in the far-infrared frequency, particularly their AO8 structure units. These results would provide useful insights into the structure-property relation in the RETi(Nb,Ta)O6 (RE: rare earth) material system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 14, 1 October 2018, Pages 16191-16198
Journal: Ceramics International - Volume 44, Issue 14, 1 October 2018, Pages 16191-16198
نویسندگان
Jian Zhang, Ruzhong Zuo,