کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7887143 1509788 2018 23 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Infrared radiation performance and calculation of B-site doped lanthanum aluminate from first principles
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Infrared radiation performance and calculation of B-site doped lanthanum aluminate from first principles
چکیده انگلیسی
Pure LaAlO3 and LaAl1-xNixO3 samples (x = 0.05, 0.1, 0.15, 0.2, 0.25, 0.3) were prepared using a sol-gel technique. The samples were analyzed and characterized using XRD, SEM, FT-IR and XPS. The results showed that the infrared emissivity of LaAl1-xNixO3 powder prepared at 1500 ℃ for 2 h increases with Ni2+ doping content. For x = 0.25, the mean emissivity in the 3-5 µm infrared spectral region was 0.835. This was a 142% increase compared with that of pure LaAlO3 (0.345). The doped Ni ions mainly exist with valences of + 2 and + 3 in the LaAlO3 lattice. After doping, the concentration of electron holes and oxygen vacancies increased, leading to an enhancement of free carrier absorption in the system. It indicated that the Ni2+ doping would introduce an impurity energy level in the forbidden band of LaAlO3 by first principles calculation, forming primarily by the hybridization of the 3d orbital electrons of the Ni ions and the 2p orbital electrons of the oxygen atoms. When x = 0.25, the band gap decreased from 3.50 eV to 0.77 eV. The impurity energy level allows for a reduction in the energy required for the electrons transferring from the valence band to the conduction band, causing increased numbers of electron transitions between the band gaps, thus enhancing free carrier absorption and increasing the infrared emissivity of the material. The LaAl1-xNixO3 oxide materials prepared in this work had excellent infrared radiation properties. As a lining material at high temperature reacting furnace, the energy loss could be reduced, the heat utilization efficiency would be greatly improved, and the utility model could be used in the field of high-temperature thermal energy saving.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 10, July 2018, Pages 11570-11575
نویسندگان
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