کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
79699 | 49364 | 2009 | 7 صفحه PDF | دانلود رایگان |
New low-band-gap copolymers, including thieno[3,2-b]thiophene and 2,1,3-benzothiadiazole, were synthesized as photovoltaic materials. Thiophene was introduced to provide extended π-conjugation length and charge transfer properties. A band gap (Egop=1.62 eV, Egec=1.51 eV) of this polymer was investigated through UV–vis spectroscopy and cyclic voltammetry. A bulk heterojunction structure of glass/indium tin oxide (ITO)/PEDOT:PSS/polymer-PCBM(1:3)/LiF/Al was fabricated for investigating photovoltaic properties. PC71BM was used as an acceptor material, due to its increased absorption in the visible region, in comparison with PC61BM. In this polymer, incident photon-to-current conversion efficiency (IPCE) was as high as 50%. Moreover, maximum power conversion efficiency (PCE) of up to 1.72% was achieved under AM 1.5 G conditions. It demonstrated relatively high VOC (0.67 V) and JSC (6.86 mA/cm2), while a low fill factor value (0.37) was obtained.
Journal: Solar Energy Materials and Solar Cells - Volume 93, Issue 11, November 2009, Pages 1932–1938