کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7990367 | 1516128 | 2018 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Simple and efficient fabrication of pomegranate-like Fe2O3@C on carbon cloth as an anode for lithium-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Pomegranate-like Fe2O3@C nanoparticles on carbon cloth (CC) as an anode for lithium-ion batteries are synthesized via a combination of dip-coating and hydrothermal synthesis. The spontaneous crosslinking reaction between sodium alginate (SA) and Fe3+ first creates a chelate compound, and then the SA-Fe3+ chelate is converted to Fe2O3@C nanoparticles after a simple hydrothermal treatment. The Fe2O3@C nanoparticles exhibit pomegranate-like morphology with an average diameter of 118â¯nm and are composed of smaller Fe2O3@C secondary nanoparticles of 13.7â¯nm. Such a hierarchical nanostructure can increase the accessible surface area of the Fe2O3@C/CC electrode, leading to enhanced electrochemical efficiency for the Li+ insertion/deinsertion reaction. Furthermore, by carefully controlling dip-coating time, the Fe2O3@C nanoparticles are individually and uniformly distributed on the CC surface, which supplies expansion space for Li+ insertion and protects the electrode from structural cracks. Owing to these structural characteristics, the Fe2O3@C/CC anode material shows superior electrochemical properties for lithium-ion batteries. The first discharge capacity is as high as 1006â¯mAh gâ1â¯at the current density of 0.2â¯Aâ¯gâ1, and it remains up to 1091â¯mAh gâ1 after 100 charge/discharge cycles, implying a stable cycling ability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 766, 25 October 2018, Pages 253-260
Journal: Journal of Alloys and Compounds - Volume 766, 25 October 2018, Pages 253-260
نویسندگان
Zhaopeng Li, Liuqing Li, Weihao Zhong, Ao Cheng, Wenhao Fu, Zhenghui Li, Haiyan Zhang,