کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
79911 | 49369 | 2009 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preparation of n-tetradecane-containing microcapsules with different shell materials by phase separation method Preparation of n-tetradecane-containing microcapsules with different shell materials by phase separation method](/preview/png/79911.png)
Microcapsules for thermal energy storage and heat-transfer enhancement have attracted great attention. Microencapsulation of n-tetradecane with different shell materials was carried out by phase separation method in this paper. Acrylonitrile–styrene copolymer (AS), acrylonitrile–styrene–butadiene copolymer (ABS) and polycarbonate (PC) were used as the shell materials. The structures, morphologies and the thermal capacities of the microcapsules were characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). The ternary phase diagrams showed the potential encapsulation capabilities of the three shell materials. The effects of the shell/core ratio and the molecular weight of the shell material on the encapsulation efficiency and the thermal capacity of the microcapsules were also discussed. Microcapsules with melting enthalpy > 100 J/g, encapsulation efficiency 66–75%, particle size<1 μm were obtained for all three shell materials.
Journal: Solar Energy Materials and Solar Cells - Volume 93, Issue 10, October 2009, Pages 1817–1822