کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7991621 1516141 2018 26 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
La doping inhibits stress production at the grain boundaries in Ni-WC coating
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
La doping inhibits stress production at the grain boundaries in Ni-WC coating
چکیده انگلیسی
Ni-WC-La2O3 wear-resistant coatings are prepared by a plasma spray method on the pure iron. The microstructure and wear resistance of the coating are investigated. After La2O3 doping, the wear resistance of modified coating was enhanced significantly. The amount of coating wear was reduced by 61.9% and the friction coefficient was reduced by 35.7% because of the La2O3 content of 1.5 wt.% compared with the Ni-WC coating. La2O3 can suppress WC precipitation along the grain boundaries, and reduce the number of cracks in the substrate near the WC phase. Furthermore, the diffusion and segregation behavior of La atoms is studied by first-principle calculation. The simulation results show that La doping can increase the bonding energy between the WC particles and the Ni substrate, consequently improve the abrasion properties of the coating. The cohesive energy of the interface is the smallest when the La atoms occupies Ni atomic sites of the interface, as result a stable Ni-WC interface is formed on the interface. A Ni-La amorphous transition layer is formed on the Ni-WC interface. Its structure has rheological properties and relaxes the thermal stress of the interface, which reduces the Ni-WC interface cracking and improves the bonding strength.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 753, 15 July 2018, Pages 688-694
نویسندگان
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