کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7993737 | 1516154 | 2018 | 15 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In situ synthesis of nori-derived sponge-like N, P-codoped C/Co3O4 composite as advanced anode material for lithium-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: In situ synthesis of nori-derived sponge-like N, P-codoped C/Co3O4 composite as advanced anode material for lithium-ion batteries In situ synthesis of nori-derived sponge-like N, P-codoped C/Co3O4 composite as advanced anode material for lithium-ion batteries](/preview/png/7993737.png)
چکیده انگلیسی
Developing environment friendly and low cost methods of fabricating advanced anode materials for lithium ion batteries (LIBs) is very important. Using nori as the precursor, we designed and synthesized the composite of nitrogen-phosphorus-codoped carbon matrixes and cobaltic oxide nanoparticles (N, P-codoped C/Co3O4) via hydrolysis of CoCl2 and calcination method. It is interested that the nori not only provided the dopant of N and P elements but also formed the sponge-like porous carbon matrices which exhibited a large specific surface area as 246.4 m2 gâ1. Both the dopants and the 3D porous carbon matrix are significantly helpful in improving the electrochemical performance of the product. Used as the anode material of LIB, N, P-codoped C/Co3O4 offered a high reversible specific capacity of 927 mA h gâ1 (the theoretical capacity of Co3O4 is 890 mA h gâ1) after 100 cycles at the current density of 100 mA gâ1 and a good rate capability of 454 mA h gâ1 at the current density of 1 A gâ1. Thus it is a promising alternative advanced anode material for LIB. In addition, the whole process is green, simple, economical and scalable and the method may be applied to synthesize other N, P-codoped carbon based composites.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 740, 5 April 2018, Pages 446-451
Journal: Journal of Alloys and Compounds - Volume 740, 5 April 2018, Pages 446-451
نویسندگان
Zifeng Wang, Xing Zhang, Yan Sun, Cuiping Wang, Hui Zhang, Yuhua Shen, Anjian Xie,