کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7994794 | 1516160 | 2018 | 27 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Li-rich nanoplates of Li1.2Ni0.13Co0.13Mn0.54O2 layered oxide with exposed {010} planes as a high-performance cathode for lithium-ion batteries
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The layered lithium-rich cathode material Li1.2Ni0.13Co0.13Mn0.54O2 crystallizes with an α-NaFeO2 structure, through which Li+ ions are transported along two-dimensional channels. In this work, nanoplates of Li1.2Ni0.13Co0.13Mn0.54O2 (NP-LNCMO) with exposed {010} planes are successfully synthesized. The formation of open structures provides unimpeded paths for Li+ ion intercalation/deintercalation. The synthesis involves the use of ethylene glycol with two hydroxyl groups as the solvent, which can also react with the transition metal ions to yield plate-like structures with exposed {010} planes. NP-LNCMO displays a high specific discharge capacity of 288.9 mAh gâ1 at 0.1 C (1 C = 300 mA gâ1) and an excellent rate capability (a discharge capacity of 109.7 mAh gâ1 at 15 C). Furthermore, negligible voltage decay occurs during 50 charge/discharge cycles. The excellent electrochemical performance of NP-LNCMO can be attributed to the formation of nanoplates with exposed electrochemically active {010} planes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 734, 15 February 2018, Pages 301-306
Journal: Journal of Alloys and Compounds - Volume 734, 15 February 2018, Pages 301-306
نویسندگان
Jili Li, Chunying Xu, Junwei Zhao, Jian Chen, Chuanbao Cao,