کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7999087 1516261 2015 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effects of surface hydroxyl group density on the photocatalytic activity of Fe3+-doped TiO2
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Effects of surface hydroxyl group density on the photocatalytic activity of Fe3+-doped TiO2
چکیده انگلیسی
The aim of the work is to study the effects of oxygen vacancy and surface hydroxyl group density on the photocatalytic activity of Fe3+-doped TiO2, and to investigate how the titanium dioxide doped with different levels of the Fe3+ influenced their physical and chemical characterizations. The photocatalysts were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), electron spin resonance (ESR), X-ray photoelectron spectroscope (XPS) and Fourier transform infrared (FTIR) spectra. The results revealed that adsorbed hydroxyl group density significantly influenced the photocatalytic activity, and a small amount of Fe3+ can act as a photo-generated hole and a photo-generated electron trap and inhibit the electron-hole recombination. The 0.10%-Fe3+-TiO2 with the highest surface hydroxyl group density revealed the maximum rate constant of 0.716 and the optimal photocatalytic degradation of MB. As Fe3+ doping levels are larger than 0.10%, the cluster of FeTi′-V¨O-FeTi′ generated gradually. This implied that an excessive amount of Fe3+ doped into TiO2 is detrimental to the photocatalytic activity due to the formation of FeTi′-V¨O-FeTi′ clusters and enhances the recombination of photogenerated electrons and holes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 632, 25 May 2015, Pages 326-334
نویسندگان
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