کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7999764 | 1516270 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Rate capability for Na-doped Li1.167Ni0.18Mn0.548Co0.105O2 cathode material and characterization of Li-ion diffusion using galvanostatic intermittent titration technique
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Spherical Li1.167âxNaxNi0.18Mn0.548Co0.105O2 (0 ⩽ x ⩽ 0.1) particles were prepared by spray pyrolysis, and subjected to electrochemical characterization for lithium battery applications. It was confirmed that Na doping enhances the charge/discharge rate capability. The structure of prepared samples was characterized by XRD: the c-axis lattice parameter increases with increase in the amount of Na ions (parameterized by x, above). The Na-doped sample with x = 0.05 shows capacities of 208 and 184 mA h gâ1 at high current densities of 1.0 C and 2.0 C, respectively. These values are enhanced, compared to values of 189 and 167 mA h gâ1 for the bare sample. The ratio of the capacity at 1.0 C to that at 0.1 C is enhanced from 77% for the bare sample to 84% for the Na-doped sample with x = 0.05. The Li diffusion coefficients obtained from the galvanostatic intermittent titration technique (GITT) are higher for Na-doped samples than for the bare sample. In particular, the Na-doped sample (x = 0.05), in the potential range around 4 V, has a higher DLi+ value of 3.34 Ã 10â9 cm2 sâ1, compared with 1.35 Ã 10â9 cm2 sâ1 for the bare sample. The Na-doped samples (0 < x < 0.075) show high capacity retention: the Na-doped sample (x = 0.05) shows a capacity retention of 92% compared to 83% for the bare sample.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 623, 25 February 2015, Pages 55-61
Journal: Journal of Alloys and Compounds - Volume 623, 25 February 2015, Pages 55-61
نویسندگان
Sung Nam Lim, Jung Yoon Seo, Dae Soo Jung, Wook Ahn, Hoon Sub Song, Sun-Hwa Yeon, Seung Bin Park,