کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
80171 | 49375 | 2009 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Electrochromic devices employing methacrylate-based polymer electrolytes Electrochromic devices employing methacrylate-based polymer electrolytes](/preview/png/80171.png)
Poly(ethyl methacrylate) (PEMA)- and poly(2-ethoxyethyl methacrylate) (PEOEMA)-based polymer gel electrolytes with entrapped solutions of lithium perchlorate in propylene carbonate (PC) were prepared by direct, UV-initiated polymerization. The electrolytes were studied using electrochemical methods and they exhibit good ionic conductivity (up to 0.7 mS cm−1 at 20 °C) as well as electrochemical stability up to 2.5 V vs. Cd/Cd2+ (5.1 V vs. Li/Li+) on gold electrode. The electrolytes have thermal stability up to 125 °C. The electrolytes were successfully tested as ionic conductors in the electrochromic device FTO/WO3/Li+-electrolyte/V2O5/FTO using coupled optoelectrochemical methods to discuss the relationship between the electrolyte composition and parameters such as change of transmittance, response time and stability. The transmittance change Δτ was found to be 30–45% at 634 nm.
Journal: Solar Energy Materials and Solar Cells - Volume 93, Issue 2, February 2009, Pages 249–255