کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8124737 | 1522773 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Application of high resolution NMR (1H and 13C) and FTIR spectroscopy for characterization of light and heavy crude oils
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
زمین شناسی اقتصادی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
High-resolution nuclear magnetic resonance (NMR) and Fourier transform infrared (FTIR) spectroscopy experiments were applied to obtain detailed information on the hydrocarbon chemistry of three light and three heavy crude oils. Quantitative fractions of aromatic molecules and functional groups constituting oil hydrocarbons were determined by 13C NMR spectroscopy and comparative analysis of the oil samples with different viscosity, origin and preliminary treatment. SARA composition and some important information about aromaticity, oxidation behavior, branching, aliphaticity and sulfurization of studied oil samples were obtained. Integral characteristics of high-resolution NMR and FTIR spectra have a great potential to study the structure and characterization of light and heavy crude oils, which could substitute present traditional fractionation procedures. Relationships between spectroscopic parameters obtained by high-resolution NMR and FTIR spectroscopy methods and crude oil compositions can be useful for fast prediction of crude oil properties due to different type of treatment, including thermal methods for enhanced oil recovery. Also quantitative proportions of functional groups obtained by NMR and spectral indices obtained by FTIR can be one of the criteria for developing fingerprint approach.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Petroleum Science and Engineering - Volume 168, September 2018, Pages 256-262
Journal: Journal of Petroleum Science and Engineering - Volume 168, September 2018, Pages 256-262
نویسندگان
I.Z. Rakhmatullin, S.V. Efimov, V.A. Tyurin, A.A. Al-Muntaser, A.E. Klimovitskii, M.A. Varfolomeev, V.V. Klochkov,