Interactions between different acids and bauxitic-based ceramic proppants used in gravel-packed and fractured wells

The results show that bauxite has a minimal solubility of 0.5 wt% in 10.0 wt% HCl. The proppant is readily soluble in different mud acids, 56.0 wt% dissolved in some cases. The amount dissolved increases with temperature, soaking time, acid concentration, and dynamic conditions. The fines generated and the changes in grain size distribution are detrimental to the proppant conductivity. 19F NMR showed aluminum fluoride complexes with different mud acids due to the high Al/F affinity. XRF showed that the solubility of the proppant occurs mainly in mullite and maghemite due to their high reactivity. Crush resistance test shows a direct relationship between solubility and mechanical strength of bauxite. Assessing solubility effects will help to better design acid treatments without jeopardizing the integrity of the proppant.