کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8328897 | 1540209 | 2018 | 37 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
C-coordinated O-carboxymethyl chitosan metal complexes: Synthesis, characterization and antifungal efficacy
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
Diethyl ether (PubChem CID: 3283)Nicotinamide (PubChem CID: 936)methanol (PubChem CID:887)Monochloroacetic acid (PubChem CID: 300)Ethanol (PubChem CID: 702) - اتانول (PubChem CID: 702)Acetic acid (PubChem CID: 176) - اسید استیک (PubChem CID: 176)Antifungal - ضد قارچCoordination - هماهنگیSodium hydroxide (PubChem CID: 14798) - هیدروکسید سدیم (PubChem CID: 14798)Chitosan (PubChem CID: 71853) - کیتوزان (PubChem CID: 71853)
موضوعات مرتبط
علوم زیستی و بیوفناوری
بیوشیمی، ژنتیک و زیست شناسی مولکولی
زیست شیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel type of O-carboxymethyl chitosan Schiff bases (O-CSPX) was synthesized via a condensation reaction. After the coordination reaction of cupric ions, zinc ions and nickel ions, metal complexes (O-CSPX-M) were achieved. The theoretical structure of O-CSPX-M calculated by Gaussian 09 reveals that the copper ions and nickel ions underwent dsp2 hybridization, the zinc ions underwent sp3 hybridization, and they all coordinated by the carbon atom in the p-Ï conjugate group. Then, the structures were confirmed by FT-IR, 1H NMR, CP-MAS 13C NMR, elemental analysis, DSC and XRD. The antifungal properties of O-CSPX-M against Phytophthora capsici (P. capsici), Gibberella zeae (G. zeae), Fusarium oxysporum (F. oxysporum) and Botrytis cinerea (B. cinerea) were evaluated at concentrations ranging from 0.05Â mg/mL to 0.40Â mg/mL. The experiments indicated that the derivatives have significantly enhanced antifungal activity after metal ions complexation compared with the original chitosan. Moreover, it was shown that 0.20Â mg/mL of O-CSPX-Cu can 100% inhibit the growth of P. capsici and 0.20Â mg/mL of O-CSPX-Ni can 87.5% inhibit the growth of B. cinerea. In addition, the phytotoxicity assay and cell viability assay were also evaluated. The experimental results may provide a novel direction for the development of metal fungicides.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Biological Macromolecules - Volume 106, January 2018, Pages 68-77
Journal: International Journal of Biological Macromolecules - Volume 106, January 2018, Pages 68-77
نویسندگان
Weixiang Liu, Yukun Qin, Song Liu, Ronge Xing, Huahua Yu, Xiaolin Chen, Kecheng Li, Pengcheng Li,