کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
870541 | 909873 | 2006 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films Enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films](/preview/png/870541.png)
چکیده انگلیسی
A novel enantioselective potentiometric sensor was constructed based on optical active polyaniline (PAn) films. The sensor with high stability showed discrimination behavior toward one isomer of racemic phenylalanine (Phe). The (−) or (+) PAn-based electrodes exhibited an excellent Nernstian slope of ∼60 mV per decade for l-Phe or d-Phe, respectively. In addition, when the sensor was exposed to the mixture of enantiomers, the slope of the response changed along with their proportions, which would be employed as an index of the enantiomeric purity of the mixture. At last, the mechanism of chiral discrimination for Phe was discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Biosensors and Bioelectronics - Volume 21, Issue 11, 15 May 2006, Pages 2184–2187
Journal: Biosensors and Bioelectronics - Volume 21, Issue 11, 15 May 2006, Pages 2184–2187
نویسندگان
Xiuli Yin, Jingjing Ding, Song Zhang, Jilie Kong,