کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8917713 | 1642778 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Molecular catalysis of electrochemical reactions
ترجمه فارسی عنوان
کاتالیزور مولکولی واکنش های الکتروشیمیایی
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
Molecular catalysis of electrochemical reactions currently attracts a lot of attention, notably concerning the transformation of small molecules in response to issues raised by modern energy challenges. This review summarizes recent advances in the mechanism analysis of multi-electrons-multi-steps processes involved in homogenous molecular catalysis of such electrochemical reactions. It also describes strategies for a rational catalyst benchmarking, through the establishment of “catalytic Tafel plots”. We show that careful analysis of through-structure and through-space substituent effects within a given family of catalyst is a powerful tool for intelligent design of new catalysts. Challenges raised by the “heterogenization” of molecular catalysts are discussed in the final section.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Current Opinion in Electrochemistry - Volume 2, Issue 1, April 2017, Pages 26-31
Journal: Current Opinion in Electrochemistry - Volume 2, Issue 1, April 2017, Pages 26-31
نویسندگان
Cyrille Costentin, Marc Robert, Jean-Michel Savéant,