کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8955098 | 1646066 | 2018 | 68 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Net fractionation of hydrogen isotopes in n-alkanoic acids from soils in the northern boreal forest
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Net fractionation of hydrogen isotopes in n-alkanoic acids from soils in the northern boreal forest Net fractionation of hydrogen isotopes in n-alkanoic acids from soils in the northern boreal forest](/preview/png/8955098.png)
چکیده انگلیسی
Plant-derived n-alkyl lipids are well-preserved in sedimentary archives, and their stable hydrogen isotope ratio (δDwax) is a proxy for precipitation δD and climate. Net fractionation of H isotopes between plant source water and n-alkyl lipids (εwax/water) is the largest uncertainty for interpreting this proxy and depends on plant type and environment. Although popular proxies, n-alkanoic acids (n-acids) are less frequently calibrated in modern environments than n-alkanes. We constrain the net fractionation (εwax/MAP - Mean Annual Precipitation) for the northern boreal forest based on n-C24,26,28 acids in topsoils from a 13-site network in Yukon, Alaska and Northwest Territories (60-68°N). n-Acid homologue distributions for common boreal plants (gymnosperm trees, shrubs, forbs, C3 grasses and mosses) show that soil n-acids are dominated by mosses, but with a reduced carbon preference index compared to fresh mosses, possibly owing to post-depositional degradation. Regionally averaged εwax/MAP values are â93â¯Â±â¯10â°, â101â¯Â±â¯11â° and â95â¯Â±â¯11â° for n-C24,26,28 acids, respectively, which are similar to values reported from low and high latitude regions. We find that εwax/MAP for n-C26,28 acids (but not n-C24) is significantly (pâ¯â¤â¯0.05) smaller with increasing latitude and decreasing mean annual temperature, factors that covary across our network. Since latitude is typically known for ancient deposits, we parsed the dataset to obtain latitude-specific εwax/MAP values for 60-64°N (â107â¯Â±â¯8â° for n-C26; and â101â¯Â±â¯8â° for n-C28) and 65-68°N (â94â¯Â±â¯11â° for n-C26; and â89â¯Â±â¯10â° for n-C28). These soil-derived values are relevant for hydroclimate reconstructions using fossil n-acids in paleosols from a comparable paleoflora and latitude.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Organic Geochemistry - Volume 125, November 2018, Pages 1-13
Journal: Organic Geochemistry - Volume 125, November 2018, Pages 1-13
نویسندگان
Aleesha Bakkelund, Trevor J. Porter, Duane G. Froese, Sarah J. Feakins,