کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8959816 | 1646359 | 2019 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of OctaphenylPolyhedral oligomeric silsesquioxane on the electrospun Poly-m-phenylene isophthalamid separators for lithium-ion batteries with high safety and excellent electrochemical performance
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
In this study, a hybrid Poly-m-phenyleneisophthalamide/Octaphenyl-Polyhedral oligomeric silsesquioxane (PMIA/Octaphenyl-POSS) membrane (HPPS) was fabricated by electrospinning technique and its application performance as lithium-ion battery separators was discussed. The organic-inorganic feature of Octaphenyl-POSS (OPS) endowed admirable compatibility of membrane matrix for the HPPS membranes. The nanofiber membranes with OPS nanoparticles were provided with commendable thermal stability, robust mechanical strength (21.79â¯MPa), high porosity and electrolyte uptake, which laid a good foundation for improving the safety and cycle performance of the cells with the separator. The lithium-ion battery with the HPPS separator displayed a high ionic conductivity of 1.93â¯Ãâ¯10â3â¯S·cmâ1 and a stable electrochemical window of 4.98â¯V. More significantly, the HPPS nanofiber membrane based Li/LiCoO2 cell exhibited excellent cycling stability with high first discharge capacity up to 157.9â¯mAh·gâ1 and superior capacity retention of 89.04% after 100 cycles. Therefore, the HPPS separator has extraordinary potential to be used in high-performance lithium-ion battery.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 356, 15 January 2019, Pages 11-21
Journal: Chemical Engineering Journal - Volume 356, 15 January 2019, Pages 11-21
نویسندگان
Huijuan Zhao, Nanping Deng, Jing Yan, Weimin Kang, Jingge Ju, Liyuan Wang, Zongjie Li, Bowen Cheng,