کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9487706 | 1330773 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxidation of caffeic acid in the presence of l-cysteine: isolation of 2-S-cysteinylcaffeic acid and evaluation of its antioxidant properties
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کلمات کلیدی
موضوعات مرتبط
علوم زیستی و بیوفناوری
علوم کشاورزی و بیولوژیک
دانش تغذیه
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چکیده انگلیسی
Caffeic acid (3,4-dihydroxycinnamic acid) was oxidized in wine-like model solutions (citrate buffer, pH 3.5) containing l-cysteine, by means of sodium periodate that mimics the mechanism of polyphenol oxidase (PPO). The reaction lead to the formation of a l-cysteine/caffeic acid adduct, which was isolated and tentatively identified as 2-S-cysteinylcaffeic acid (2-CCA), on the basis of LC-MS and 1H NMR data. The antioxidant properties of 2-CCA were assessed by employing the DPPH and a ferric-reducing test, and compared with both caffeic acid and l-cysteine, but also with gallic acid, which was used as a reference antioxidant. The results indicated that the adduct exhibits slightly improved antiradical activity in relation with the parent molecule (caffeic acid), but its reducing capacity was dramatically reduced, a fact that was theoretically ascribed to its strong chelating ability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Food Research International - Volume 38, Issue 4, May 2005, Pages 395-402
Journal: Food Research International - Volume 38, Issue 4, May 2005, Pages 395-402
نویسندگان
Daniel Bassil, Dimitris P. Makris, Panagiotis Kefalas,