کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9559237 1381146 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A new strategy for the one-step synthesis of block copolymers through simultaneous free radical and ring opening polymerizations using a dual-functional initiator
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
A new strategy for the one-step synthesis of block copolymers through simultaneous free radical and ring opening polymerizations using a dual-functional initiator
چکیده انگلیسی
Block copolymers are fascinating and complex materials that have been used in a range of diverse scientific and technological capacities. We demonstrate that a single one-step approach based on dual simultaneous polymerizations is a viable technique for the synthesis of a wide range of block copolymers by combining two dissimilar polymerization systems and using a dual-functional initiator. The main advantage of this methodology is that a simple, one-step, and simultaneous polymerization occurs in the bulk, which makes this process very attractive from both industrial and academic points of view. We plan to study the reaction kinetics and evaluate how well the ring opening catalyst [in this case, Sn(oct)2] works under reverse ATRP conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 5, 14 February 2005, Pages 1561-1565
نویسندگان
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