کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9560583 | 1381994 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Composition, structure and thermal degradation of hemp cellulose after chemical treatments
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The thermal degradation behaviour of hemp (Cannabis sativa L.) fibres under a nitrogen atmosphere was investigated by using thermogravimetry (TGA). The kinetic activation energy of treated fibres was calculated from TGA data by using a varied heating rate from 2.5 to 30 °C/min. The greater activation energy of treated hemp fibre compared with untreated fibre represented an increase of purity and improvement in structural order. A hydrophobic solvent affected the degree of non-cellulosic removal. Mercerisation and enzyme scouring removed non-cellulosic components from the fibre; however, structural disruption was observed after higher alkaline concentration, 20 %wt/v and longer scouring time, respectively. Structural disruption was observed by X-ray measurement. The FTIR results indicated an elimination of the non-cellulosic components by the mercerisation treatment and a specific removal of low methoxy pectin by use of pectate lyase enzyme (EC 4.2.2.2). An increase of temperature at the maximum rate of degradation and the rate of weight loss was characteristic of the purity and structure of treated hemp fibre.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 89, Issue 2, August 2005, Pages 327-335
Journal: Polymer Degradation and Stability - Volume 89, Issue 2, August 2005, Pages 327-335
نویسندگان
S. Ouajai, R.A. Shanks,