کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9585217 | 1505783 | 2005 | 15 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Determination of the local chemistry of iron in inorganic and organic materials
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Determination of the local chemistry of iron in inorganic and organic materials Determination of the local chemistry of iron in inorganic and organic materials](/preview/png/9585217.png)
چکیده انگلیسی
The systematic EELS analysis of a series of naturally occurring, synthetic and biological samples has provided a framework from which Fe valence of unknown materials can be determined and the relative ratios of the valences present can be calculated. The quantification of the relative ratios of Fe3+/Fe2+ is possible via the fitting of Gaussian or Voigt (with 89.3% Gaussian contribution) line profiles to the Fe L3-edge. The ratio of Fe3+/ΣFe is determined from the areas under the fitted peaks. The method is robust and has an error in the range of <10% on Fe3+/ΣFe for samples with >2 atom% Fe. We present applications of this method including the investigation of polaron hopping in calcic amphibole, the quantification of Fe3+/ΣFe in clay minerals from deep water sediments, quantification of Fe valence in human liver tissue and the determination of Fe valence in airborne particulate matter.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 143, Issues 2â3, May 2005, Pages 173-187
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 143, Issues 2â3, May 2005, Pages 173-187
نویسندگان
Clair C. Calvert, Andy Brown, Rik Brydson,