کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9589418 | 1393797 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High-resolution Fourier transform spectrum of H2S in the region of the second hexade
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
High-resolution Fourier transform infrared spectrum of H232S was recorded and analyzed in the region of the second hexade v=v1+12v2+v3=2.5. More than 1700 transitions were assigned to the 2ν1 + ν2, ν1 + ν2 + ν3, ν1 + 3ν2, 3ν2 + ν3, 5ν2, and ν2 + 2ν3 bands with the maximum value of quantum number J equal to 18, 18, 13, 11, 13, and 9, respectively. The theoretical analysis was fulfilled with a Hamiltonian model which takes into account numerous resonance interactions between all the vibrational states in this polyad. By a least-square fitting, finally 505 upper energy levels were reproduced by 80 parameters with an rms deviation of 0.0019 cmâ1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 234, Issue 2, December 2005, Pages 270-278
Journal: Journal of Molecular Spectroscopy - Volume 234, Issue 2, December 2005, Pages 270-278
نویسندگان
O.N. Ulenikov, A.-W. Liu, E.S. Bekhtereva, O.V. Gromova, L.-Y. Hao, S.-M. Hu,