کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9589495 | 1393808 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The infrared spectrum of the AsD radical in its X3룉 state, recorded by laser magnetic resonance
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The infrared spectrum of the AsD radical in its X3Σâ state, recorded by laser magnetic resonance The infrared spectrum of the AsD radical in its X3Σâ state, recorded by laser magnetic resonance](/preview/png/9589495.png)
چکیده انگلیسی
The infrared spectrum of the AsD radical in the X3Σâ ground state has been recorded using CO laser magnetic resonance. The radical was formed by the reaction between D atoms and arsenic powder. Low-N transitions in the fundamental band and in the (2-1) and (3-2) hot bands have been detected. Hyperfine structure from the 75As nucleus (I = 3/2) is seen on many of the resonances. These measurements have been combined with information from previous measurements of rotational transitions at sub-millimeter wavelengths [H. Fujiwara, K. Kobayashi, H. Ozeki, S. Saito, A.I. Jaman, J. Chem. Soc. Faraday Trans. 93 (1997) 1045-1051] to determine an extended and improved set of molecular parameters for 75AsD. Comparison is made with corresponding parameter values for AsH.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 232, Issue 2, August 2005, Pages 167-173
Journal: Journal of Molecular Spectroscopy - Volume 232, Issue 2, August 2005, Pages 167-173
نویسندگان
Jesús Flores-Mijangos, Heiko Ganser, John M. Brown,