Ir-based additives for NO reduction and CO oxidation in the FCC regenerator: Evaluation, characterization and mechanistic studies

NO reduction and CO oxidation take place thermally at 700 °C. Increasing the O2 concentration in the feed favors CO oxidation at the expense of NO reduction. With 500ppmIr/CPBase and 1000ppmIr/CPBase additives, complete NO reduction and CO oxidation is achieved in the presence of 40% excess oxygen. Higher oxygen excess, however, reduces or eliminates the NOx reduction activity of these materials. IR studies suggest that NO reduction by CO proceeds on Ir/alumina additives via the dissociative adsorption of NO, the formation of NCO species on Ir and their migration to the alumina support, where N2 and CO2 are formed. IR spectroscopy indicates that Ce modifies the Ir surface enhancing the CO oxidation and enabling NO reduction via the NO2 formation.