کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9609826 46563 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
An investigation on the mechanism of NO decomposition over Rh/SiO2 catalysts in presence of pulse injected H2
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
An investigation on the mechanism of NO decomposition over Rh/SiO2 catalysts in presence of pulse injected H2
چکیده انگلیسی
Rh/SiO2 catalysts were prepared by sol-gel, micro-emulsion and grafting methods. They were characterized by BET, EDXRF and TEM. Their catalytic activity was studied for NO decomposition under steady state transient conditions with pulse injected H2. The reactions were carried out in the temperature range of 100-400 °C. NO, N2O, NO2, O2, H2, NH3, N2 and H2O were monitored and analyzed by mass spectroscopy. Rh/SiO2 catalysts were highly active and selective for NO reduction to N2. H2 pulse experiments revealed that pulse injected H2 removed the adsorbed atomic oxygen and nitrogen species from the catalyst surface to form water and NH3, respectively. Based on the pulse experiments, the mechanism for the formation of N2, H2O, NH3 and N2O has been proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis B: Environmental - Volume 60, Issues 1–2, 1 September 2005, Pages 65-71
نویسندگان
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