کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9614395 | 48537 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Palladium-catalysed reduction of heteroaromatic naphthyl ethers: Structural effects on reactivity
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Palladium-catalysed reduction of heteroaromatic naphthyl ethers: Structural effects on reactivity Palladium-catalysed reduction of heteroaromatic naphthyl ethers: Structural effects on reactivity](/preview/png/9614395.png)
چکیده انگلیسی
Experimental conditions for palladium-catalysed hydrogenolysis of tetrazolyl and benzisothiazolyl naphthylmethylic ethers, with a hydrogen donor and with molecular hydrogen, were investigated. Analysis of the structure and reactivity indicates that these compounds are structurally similar to the corresponding benzyloxyderivatives around the ether bond but exhibit different reactivity. It can be concluded from this investigation that 5-chloro-1-phenyltetrazole acts as a better derivatizing agent for naphthyl methanols than 3-chloro-1,2-benzisothiazole-11-dioxide, this contrasting with what has been observed with phenols, allylic and benzylic alcohols.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 242, Issues 1â2, 1 December 2005, Pages 241-250
Journal: Journal of Molecular Catalysis A: Chemical - Volume 242, Issues 1â2, 1 December 2005, Pages 241-250
نویسندگان
LuÃs M.T. Frija, M. Lurdes S. Cristiano, Emanuel M.O. Guimarães, Nelson C. Martins, Rui. M.S. Loureiro, Jamie F. Bickley,