کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9617667 | 49176 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The synthesis of large crystals of zeolite Y re-visited
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The synthesis of large crystals of zeolite Y re-visited The synthesis of large crystals of zeolite Y re-visited](/preview/png/9617667.png)
چکیده انگلیسی
The major synthesis routes described in the literature so far for zeolite Y (FAU) with an elevated nSi/nAl-ratio and larger crystallite sizes were systematically re-investigated. Syntheses in the presence of triethanolamine with or without added bis(2-hydroxyethyl)dimethylammonium chloride yielded large crystals (10-100 μm) of faujasite-type zeolites. However, only products with low nSi/nAl-ratios below 1.8 were obtained, and zeolite P was an inevitable side product or even the main product. Furthermore, the outcome of these syntheses was poorly reproducible. Following another known literature procedure, phase-pure zeolite Y could be obtained with the cyclic polyether 15-crown-5 as a structure-directing agent. The influence of ageing, homogenization and seeding of the synthesis gel, the crystallization time and temperature, different Si- and Al-sources and the addition of NaF as a mineralizer or of co-templates such as triethanolamine, ethylene glycol or 1,3,5-trioxane on the resulting product was investigated. A carefully optimized procedure led to large crystals of highly phase-pure zeolite Y with well defined octahedral morphology and a narrow crystal size distribution in the range of 4-5 μm. Such crystals can be reproducibly synthesized in high yields with an nSi/nAl-ratio of 3.4-4.0. Neither crystallization seeds nor an ageing of the synthesis gel before hydrothermal crystallization are required.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 83, Issues 1â3, 1 September 2005, Pages 333-344
Journal: Microporous and Mesoporous Materials - Volume 83, Issues 1â3, 1 September 2005, Pages 333-344
نویسندگان
Christine Berger, Roger Gläser, Rainer A. Rakoczy, Jens Weitkamp,