کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9617680 | 49160 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Local environment of manganese incorporated in mesoporous MCM-41
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Manganese containing MCM-41 was synthesised by the direct hydrothermal method (DHT) in the presence of cetyltrimethylammonium chloride (CTACl) as a template. The local environment of manganese incorporated in mesoporous silicate MCM-41 was investigated by XAS (X-ray Absorption Spectroscopy). XANES (X-ray Absorption Near Edge Structure) studies showed the coexistence of Mn2+ and Mn3+ cations in both, as-synthesised and template-free MnMCM-41 samples. The major part of manganese cations in the as-synthesised MnMCM-41 was Mn2+, while in the template-free MnMCM-41 the amount of Mn3+ was increased. EXAFS (X-ray Absorption Fine Structure) analyses revealed that major part of manganese cations in the as-synthesised MnMCM-41 were extra-framework with the Mn-O distance of 2.19Â Ã
. Manganese cations in the template-free MnMCM-41 were incorporated into the framework and coordinated to three oxygens in the first coordination shell, with two of them at a shorter distance of 1.92Â Ã
and one at a longer distance of 2.21Â Ã
. Pulsed ESR (Electron Spin Resonance) and ESEEM (Electron Spin-Echo Envelope Modulation) investigations were in agreement with the XANES and EXAFS results.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 82, Issues 1â2, 5 July 2005, Pages 129-136
Journal: Microporous and Mesoporous Materials - Volume 82, Issues 1â2, 5 July 2005, Pages 129-136
نویسندگان
NataÅ¡a Novak TuÅ¡ar, NataÅ¡a Zabukovec Logar, Gilberto Vlaic, Iztok ArÄon, Denis ArÄon, Nina Daneu, VenÄeslav KauÄiÄ,