کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9617797 | 49174 | 2005 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Adsorption equilibrium and kinetics of branched hexane isomers in pellets of BETA zeolite
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Adsorption equilibrium and kinetics of branched hexane isomers in pellets of BETA zeolite Adsorption equilibrium and kinetics of branched hexane isomers in pellets of BETA zeolite](/preview/png/9617797.png)
چکیده انگلیسی
Sorption equilibrium and kinetics of hexane isomers: n-hexane (nHEX), 3-methylpentane (3MP), 2,3-dimethylbutane (23DMB) and 2,2-dimethylbutane (22DMB) were studied in commercial pellets of zeolite BETA in the form HBEA with a Si/Al ratio of 150, between temperatures of 423 and 523Â K and partial pressures up to 0.3Â bar. Four different models were used to interpret the equilibrium data, named: Langmuir, multi-site Langmuir, dual-site Langmuir and Toth. The affinity to the adsorbent measured by the Henry's constants decreases with the degree of branching, with selectivities that can reach a value of 8.8 between nHEX and 22DMB. The heats of adsorption at zero coverage decrease with the degree of branching, being: 63.4Â kJ/mol for nHEX, 59.7Â kJ/mol for 3MP, 57.1Â kJ/mol for 23DMB and 53.6Â kJ/mol for 22DMB. However, the isosteric heat of sorption changes with coverage with a different behavior for the three isomers. Sorption kinetics studied by the Zero Length Chromatography (ZLC) technique allowed us to find the nature of controlling the diffusion mechanism (macropore or micropore); for nHEX and 3MP macropore diffusion is controlling with activation energies similar to the heats of sorption at zero coverage. For 23DMB and 22DMB, the controlling mechanism changes, being the system governed apparently by both macropore and micropore diffusion. Data from this work are also compared with those reported in literature for both zeolite BETA and silicalite.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 79, Issues 1â3, 1 April 2005, Pages 145-163
Journal: Microporous and Mesoporous Materials - Volume 79, Issues 1â3, 1 April 2005, Pages 145-163
نویسندگان
Patrick S. Bárcia, José A.C. Silva, AlÃrio E. Rodrigues,