کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9617854 | 49182 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Alkali-containing mesoporous (alumino) silicate materials with very high metal loading
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
Mesoporous aluminosilicates with Si/Al ratios ranging from approximately 1 to â (for a pure-silica compound) have been synthesized in the presence of sodium and cetyl trimethyl ammonium (CTMA+) cations. All materials are thermally stable and retain their highly ordered hexagonal structure upon removal of surfactant molecules at 800Â K. Original procedures have been explored to exchange selectively surfactant and/or sodium cations from as-made materials. Treatments in water exchange exclusively sodium ions, without extracting surfactant molecules, whilst treatments in ethanol remove preferentially organic molecules. Combining these two procedures allowed us to exchange completely CTMA+ and Na+ cations and to prepare highly ordered Li+, K+, Cs+ and Ca2+-modified materials with very high alkali metal concentrations. The stability of the exchanged mesoporous compounds depends on the aluminum content and on the nature of the alkali cation. All materials are particularly stable upon exchange with Li+ and Ca2+ cations. By contrast, the stability of solids exchanged with Cs+ or K+ cations decreases with decreasing the aluminum content. In the particular case of pure silica MCM-41, the hexagonal structure is retained upon exchange of surfactant molecules with Li+ and Ca2+ cations but is severely damaged with other cations. The procedures reported here are not only efficient to introduce a large amount of cations in mesoporous materials, but they can also be used to remove completely surfactant molecules from MCM-41 under mild conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 77, Issues 2â3, 26 January 2005, Pages 147-157
Journal: Microporous and Mesoporous Materials - Volume 77, Issues 2â3, 26 January 2005, Pages 147-157
نویسندگان
Natacha Lang, Alain Tuel,