کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9625614 459856 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The effect of chain microstructure on electrochemical and spectroelectrochemical properties of fluorenone-dialkyl bithiophene alternate copolymers
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The effect of chain microstructure on electrochemical and spectroelectrochemical properties of fluorenone-dialkyl bithiophene alternate copolymers
چکیده انگلیسی
Voltammetric and spectroelectrochemical behavior of two newly synthesized conjugated polymers, which show the same chemical constitution but different type of regioregularity, is compared. These are poly(fluorenone-alt-dioctyl bithiophene)s in which the alkylthiophene rings are either head to head (HH) or tail to tail (TT) coupled, termed PFDOBT-HH and PFDOBT-TT, respectively. Both polymers can be electrochemically p- and n-doped and show the electrochemical energy gap (Egel) of the order of 2 eV. In the oxidation side of the voltammogram PFDOBT-HH gives a relatively narrow anodic peak with a maximum at E = 0.78 V versus Fc/Fc+. The corresponding peak of PFDOBT-TT is much broader with the maximum shifted to slightly lower potentials (E = 0.74 V versus Fc/Fc+). UV-vis-NIR and Raman spectroelectrochemical studies confirm that the oxidative doping of PFDOBT-TT starts at lower potentials and indicate significant differences in the anodic oxidation in both cases. In PFDOBT-HH the doping is sequential, which means that it starts by the oxidation of the bithiophene sub-units and is completed by the oxidation of the fluorenone ones. In the case of PFDOBT-TT both sub-units are doped simultaneously.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 50, Issues 7–8, 15 February 2005, Pages 1597-1603
نویسندگان
, , , , , ,