کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9675659 | 1454103 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of some organic surfactants on the electrochemical behaviour of carbon steel in formation water
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
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چکیده انگلیسی
The effect of adding some organic surfactants, cocamide diethanol amine as a nonionic surfactant (NS), cetrimonium chloride as a cationic surfactant (CS), and cocamidopropyl betaine as an amphoteric surfactant (AmS), on the electrochemical behaviour of carbon steel in formation water was investigated by using a potentiodynamic and impedance techniques. Results reported in this study show that the addition of these surfactants inhibits the corrosion of carbon steel and the extent of inhibition depends upon the type and concentration of the surfactant. The inhibition efficiency for three organic surfactants increase with the increase in the surfactants concentration but decrease with increasing temperature. The inhibition efficiency of each of AmS, NS, and CS reaches a maximum value around their critical micelle concentrations. The percentage of corrosion inhibition of these surfactants decreases in the order AmSÂ >Â NSÂ >Â CS. The inhibition occurs through adsorption of the organic surfactants on the metal surface without modifying the mechanism of corrosion process. The experimental data fit both of Flory-Huggins and kinetic-thermodynamic isotherm.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 266, Issues 1â3, 15 September 2005, Pages 129-140
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 266, Issues 1â3, 15 September 2005, Pages 129-140
نویسندگان
S.T. Keera, M.A. Deyab,