کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9675949 | 1454111 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Surface-enhanced Raman scattering studies on the recognition mechanism of glutathione peroxidase mimics, bis-cyclodextrin diselenide
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Surface-enhanced Raman scattering studies on the recognition mechanism of glutathione peroxidase mimics, bis-cyclodextrin diselenide Surface-enhanced Raman scattering studies on the recognition mechanism of glutathione peroxidase mimics, bis-cyclodextrin diselenide](/preview/png/9675949.png)
چکیده انگلیسی
Surface-enhanced Raman scattering (SERS) spectroscopy has been used to explore the recognition mechanism between a selenium-containing glutathione peroxidase (GPX) mimic, 2,2â²-diseleno-bis-β-cyclodextrin (2-SeCD) and two glutathione (GSH) alternatives, S-dinitrophenyl-glutathione (GSH-S-DNP) and 4,4â²-bis(carboxymethyleneoxy)azobenzene (BCMAB). SERS spectra have been employed to investigate how these alternatives bind with β-CD and 2-SeCD. SERS signals of the spectra of GSH-S-DNP and BCMAB are much intense in comparison with those of theirs complexes, GSH-S-DNP/CDs and BCMAB/CDs in silver colloid solutions, which suggest that GSH-S-DNP and BCMAB are included into the CD cavity when they bind with β-CD or 2-SeCD. Weak Raman signals in the SERS spectra of the GSH-S-DNP/CDs in silver colloid solution make it difficult to investigate the recognition mechanism between CDs and GSH-S-DNP by using SERS efficiently. The bands at 1388 and 1379 cmâ1 in the SERS spectra of BCMAB/CDs strongly suggest that BCMAB does not bind with β-CD or 2-SeCD via its COOH group.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volumes 257â258, 5 May 2005, Pages 111-115
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volumes 257â258, 5 May 2005, Pages 111-115
نویسندگان
Ya-Qiong Hao, Yuqing Wu, Lixin Wu, Junqiu Liu, Guimin Luo,