کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9675999 | 1454111 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Studies on the interaction between tetradecyl dimethyl betaine and sodium carboxymethyl cellulose by DPD simulations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
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چکیده انگلیسی
The dissipative particle dynamics (DPD) simulation method has been used to investigate the effect of pH value on the interaction between tetradecyl dimethyl betaine (C14BE) and sodium carboxymethyl cellulose (Na-CMC) in aqueous solution. The simulation results indicate that C14BE/Na-CMC aggregate does not form at pHÂ =Â 7 (the isoelectric point pI of C14BE is 5), but at pHÂ =Â 2 typical C14BE/Na-CMC aggregate is observed, which means the interactions between them get stronger. Furthermore, at pHÂ =Â 2 the curve of the end-to-end distance of Na-CMC chain as a function of C14BE volume fraction initially increases, then reduce and finally increase; while at pHÂ =Â 7 its end-to-end distance remains constant. The results of surface tension measurements are consistent with DPD simulation results. It is concluded that DPD simulation method can provide some important information on surfactants and macromolecules at the molecular level.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volumes 257â258, 5 May 2005, Pages 385-390
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volumes 257â258, 5 May 2005, Pages 385-390
نویسندگان
Yiming Li, Guiying Xu, Yuxia Luan, Shiling Yuan, Zhiqing Zhang,