کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9684671 | 1456208 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Investigation of phase structure, sintering, and permeability of perovskite-type Ba0.5Sr0.5Co0.8Fe0.2O3âδ membranes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The high temperature phase structures of the perovskite-type oxide Ba0.5Sr0.5Co0.8Fe0.2O3âδ (BSCF) were characterized by in situ high-temperature X-ray diffraction, which revealed that BSCF exhibits a good phase reversibility and structure stability in air from room temperature to 1273 K. The XRD patterns of BSCF oxide at 1173 K in different atmospheres (air, 2% O2 in Ar and pure Ar) indicated that BSCF possesses an excellent phase stability at high temperatures not only in air but also in pure Ar. From the plot of the lattice constant against the temperature, the thermal expansion coefficient of BSCF was determined to be 11.5 Ã 10â6 Kâ1, which is smaller than that of SrCo0.8Fe0.2O3âδ (SCF) (17.9 Ã 10â6 Kâ1). Microstructures of the membranes sintered under different conditions were characterized by scanning electron microscopy (SEM). The effect of microstructure on the oxygen permeation flux through BSCF was observed by measuring the oxygen permeation flux using samples sintered under different conditions. The oxygen permeation flux increased considerably with the increase of the grain size of the membrane.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 262, Issues 1â2, 1 October 2005, Pages 20-26
Journal: Journal of Membrane Science - Volume 262, Issues 1â2, 1 October 2005, Pages 20-26
نویسندگان
Haihui Wang, Cristina Tablet, Armin Feldhoff, Jürgen Caro,