کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9743880 | 1491201 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Highly selective chromogenic ionophores for the recognition of chromium(III) based on a water-soluble azocalixarene derivative
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new water-soluble chromium-selective chromogenic azocalix[4]arene had been synthesized from diazo coupling reaction between calix[4]arene and diazonium salts, and characterized by 1H NMR, IR,UV and element analysis. It possesses an absorbance maximum at 365 nm in buffered aqueous environment, but addition of chromium(III) ion induced a weak blue shift to 350 nm and a new absorption peak at 520 nm (bathochromic shift of 155 nm), exhibited an isosbestic point at 470 nm. It is more noticeable that the absorbance at 520 nm increases along with the augment of the concentration of chromium(III) ion. Based on this, a simple and selective spectrophotometric method was developed for the determination of chromium(III), in the range of 9.35 Ã 10-4 to 4.45 Ã 10â3 mol Lâ1 of chromium(III) the linear regression equation was determined to be: absorbance (A) = 0.001 Ã C (10â4 mol Lâ1 chromium(III)) + 0.2379, r = 0.998, n = 6.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 535, Issues 1â2, 11 April 2005, Pages 183-187
Journal: Analytica Chimica Acta - Volume 535, Issues 1â2, 11 April 2005, Pages 183-187
نویسندگان
Lilin Lu, Shufang Zhu, Xingzhong Liu, Zhizhong Xie, Xi Yan,