کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9748189 | 1492990 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Compositional analysis of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by pyrolysis-gas chromatography in the presence of organic alkali
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Compositional analysis of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by pyrolysis-gas chromatography in the presence of organic alkali Compositional analysis of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by pyrolysis-gas chromatography in the presence of organic alkali](/preview/png/9748189.png)
چکیده انگلیسی
Copolymer composition of a biodegradable aliphatic copolyester, poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (P(3HB-co-3HV)) with a wide range of 3HV contents (ca. 4-23Â mol%) was determined by pyrolysis-gas chromatography (Py-GC) in the presence of tetramethylammonium hydroxide (TMAH). Nine major peaks of methylated products, five of which were attributed to the products from 3HV unit and the other four from 3HB unit, were commonly observed in the pyrograms. The copolymer compositions of P(3HB-co-3HV) samples estimated based on the relative intensities of these peaks were consistent with those by 1H NMR. These results demonstrated that Py-GC in the presence of TMAH can be applied to the accurate and highly sensitive compositional analysis of P(3HB-co-3HV) using trace amounts (ca. 0.1Â mg or less) of the samples. Furthermore, the fact that a small amount (ca. 1%) of the pyrolyzate from 3HV unit was also observed on the pyrogram of a commercially available poly(3-hydroxybutyrate), PHB, suggested that the given PHB might be actually a copolymer containing minor amount of 3HV unit.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Analytical and Applied Pyrolysis - Volume 74, Issues 1â2, August 2005, Pages 193-199
Journal: Journal of Analytical and Applied Pyrolysis - Volume 74, Issues 1â2, August 2005, Pages 193-199
نویسندگان
Hiroaki Sato, Masuki Hoshino, Hiromi Aoi, Teruyuki Seino, Yasuyuki Ishida, Keigo Aoi, Hajime Ohtani,