کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9748885 1493795 2005 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation of pyrenebutyric acid bonded silica stationary phases for the application to the separation of fullerenes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Preparation of pyrenebutyric acid bonded silica stationary phases for the application to the separation of fullerenes
چکیده انگلیسی
A novel immobilization method was proposed for the preparation of pyrenebutyric acid-bonded silica (PYB-silica) stationary phases. The pyrene moiety was grafted to silica gel through spacers of aminoalkyl silanes. The HPLC separation of C60, C70 and higher fullerenes on the new pyrenebutyric acid-bonded silica stationary phases was also studied. Based on the temperature effect, the intermolecular interaction between stationary phases and solutes and the retention mechanism were discussed. The results of column loading capacity test demonstrated the potential for the separation of fullerenes in large amounts on the PYB-silica stationary phases.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1083, Issues 1–2, 12 August 2005, Pages 23-31
نویسندگان
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