کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9757701 | 1496386 | 2005 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Polymorphism of ceramide 6: a vibrational spectroscopic and X-ray powder diffraction investigation of the diastereomers of N-(α-hydroxyoctadecanoyl)-phytosphingosine
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A preparative chromatographic method was developed for the quantitative isolation of the diastereomers of synthetic N-(α-hydroxyoctadecanoyl)-phytosphingosine (dl-CER6). The l- and the d-compound were studied each by means X-ray powder diffraction, FT-Raman and FT-IR spectroscopy. The diastereomers exhibit different thermotropic polymorphism. Three lamellar crystalline and a lamellar liquid crystalline phase were found for l-CER6. The natural occurring d-CER6 forms an Lα phase with a larger repeating distance than the l-CER6. The two lamellar crystalline phases of the d-compound have a significant larger dimension than those of the l-compound. The addition of water lowers the phase transition temperatures but does not induce structural changes such as incorporation into the lamellar sheets.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemistry and Physics of Lipids - Volume 133, Issue 1, January 2005, Pages 89-102
Journal: Chemistry and Physics of Lipids - Volume 133, Issue 1, January 2005, Pages 89-102
نویسندگان
Steve Raudenkolb, Siegfried Wartewig, R.H.H. Neubert,