کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9763747 | 1498852 | 2005 | 22 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Strict self-assembly of polymetallic helicates: the concepts behind the semantics
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
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چکیده انگلیسی
The theoretical and rational modelling of self-assembly processes is far less developed than the flourishing structural characterization of the resulting sophisticated and aesthetically appealing polymetallic architectures. However, an eventual predictive design based on molecular programming requires a detailed understanding of the chemical and physical concepts controlling self-assembly. Although the kinetic and thermodynamic background of multicomponent complexation processes remain suspicious to synthetic chemists, the recent development of two simple and complementary models for rationalizing the formation of polymetallic helicates opens the possibility of reliable predictions for the properties of multimetallic one-dimensional oligomers. The origin, theoretical base, and application of this approach for the modelling of helicates is discussed, together with its limitations and extensions toward multi-dimensional complexes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 249, Issues 5â6, March 2005, Pages 705-726
Journal: Coordination Chemistry Reviews - Volume 249, Issues 5â6, March 2005, Pages 705-726
نویسندگان
Claude Piguet, Michal Borkovec, Josef Hamacek, Kornelia Zeckert,