کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9770139 | 1501940 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
DFT theoretical, synthesis, X-ray diffraction and IR studies on new dinuclear copper macrocyclic complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: DFT theoretical, synthesis, X-ray diffraction and IR studies on new dinuclear copper macrocyclic complexes DFT theoretical, synthesis, X-ray diffraction and IR studies on new dinuclear copper macrocyclic complexes](/preview/png/9770139.png)
چکیده انگلیسی
Two symmetric dinuclear copper (II) macrocyclic complexes ([Cu2L](ClO4)2 and [Cu2Lâ²](ClO4)2) were unexpectedly obtained by the cyclocondensation between N,Nâ²-bis(3-formyl-5-n-butylsalicylidene)ethylenediimine and 1,3-diaminopropane in the presence of copper (II) perchlorate and characterized by some physical methods. Both complexes were determined by X-ray diffraction techniques. DFT theoretical calculation was used to discuss the structure and to assign the IR spectra of the cation of the complex ([Cu2L](ClO4)2, the complete vibration spectral analysis was performed. A good agreement is obtained between DFT theoretical calculation results and the experimental data for the complex ([Cu2L](ClO4)2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 743, Issues 1â3, 31 May 2005, Pages 59-68
Journal: Journal of Molecular Structure - Volume 743, Issues 1â3, 31 May 2005, Pages 59-68
نویسندگان
H. Zhou, Z.H. Peng, Z.Q. Pan, D.C. Li, B. Liu, Z. Zhang, R.A. Chi,